Recently, there has been some confusion about the first appearance of Iron Man. It is understandable. He appeared in several different comics before Tony Stark appeared in Iron Man #1.
The first appearance of Iron Man, in a grey suit, was in Tales of Suspense 39. This classic issue was written by Stan Lee. In addition, Iron Man appeared in the one-shot of Iron Man Sub-Mariner #1 before Iron Man 1.
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